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Sumitomo Chemical introduces new LCPs for 5G applications
Source:Adsale Plastics Network    Editor:JK    Date:04.May.2020

Sumitomo Chemical Advanced Technologies has introduced new liquid crystal polymers (LCPs) with very-low and consistent dielectric constant and very-low dissipation factor (loss tangent), and is offering data to help electrical engineers better understand and simulate the performance of these materials.

 

Designers developing electronic devices for 5G face many challenges. One issue is that many 5G applications (like autonomous driving) will require near-real-time access to large volumes of rapidly changing data with minimal delay or distortion in order to mimic human reaction times and ensure safe operation of self-driving vehicles.


That necessitates that materials used in connectors, cables, and other components deliver very-low latency and very-low signal loss.


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5G applications like autonomous driving requires near-real-time access to large volumes of rapidly changing data.

 

Another problem is managing the thermal load caused by the quadruple challenges of continuing interconnect densification and device miniaturization, plus the need to operate at much higher processing speeds and frequencies (in the gigahertz range), all of which increase device operating temperatures and make it harder to disperse such heat.

 

That necessitates use of materials with broader levels of thermal and hydrolytic stability to ensure consistent performance and data transmittance in the heat and humidity of a Florida summer as well as a cold, dry Wyoming winter.

 

The electronics industry also is challenged by shorter development cycles and the need to find cost-effective solutions to ensure the 5G rollout is affordable for a large number of companies and individuals.

 

To meet these trends, Sumitomo Chemical has expanded its LCP offerings with two thermotropic, injection moldable or extrudable polyester-based LCP grades specifically formulated to meet the needs of 5G.

 

SumikaSuper E6205L and SumikaSuper SR1205L, both are characterized by lower dielectric constant values than standard LCP grades — a property necessary to enable reliable, higher volume data transmission.


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The dielectric constant data for SumikaSuper SR1205L LCP at -40°C, 22°C, 80°C, and 120°C and frequencies ranging from 1 to 25 GHz.


However, owing to the fact that it has been designed using a new LCP base chemistry, SR1205L is further distinguished by its lower dissipation factor (lower loss tangent), critical for ensuring reliable data transmission even in the gigahertz / millimeter-wave frequency ranges.

 

Novel chemistry and polymerization technology also bring other benefits to the SR1205L grade. To assist electrical engineers in better understanding the relationship between material properties and electrical behavior, as well as to improve simulation accuracy, Sumitomo has retained an independent testing firm to develop performance data on SR1205L at different frequencies, temperatures, and humidity levels.

 

Testing has shown that the polymer offers very consistent dielectric constant over a broad range of temperatures (-40°C, 22°C, 80°C, and 120°C) and frequencies (1 to 25 GHz) and does a better job of retaining its tensile strength vs. standard polyester-based LCPs even at high temperatures (120°C), relative humidity levels (100% RH), and pressures (2 atm) for up to 200 hours thanks to higher hydrolysis resistance. (Initial testing of E6205L shows similar trends.) In other physical, mechanical, and processing properties, the new grades perform much like standard LCPs.

 

LCPs are a family of polymers that produce thermoplastic parts with unique processing characteristics and high performance, which is why they are commonly used to replace metals, ceramics, and other plastics.

 

Most commercial LCPs are aromatic polyesters characterized by high thermal and mechanical performance, inherent flame retardancy, good weatherability, good electrical properties, high resistance to stress cracking, and chemical inertness.

 

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SumikaSuper SR1205L has demonstrated low and consistent dielectric loss tangent (dissipation factor) over a broad range of temperatures (-40°C, 22°C, 80°C, and 120°C) and frequencies (1 to 25 GHz).


This makes them ideal for use in electrical and electronic components (including fiberoptic cables, printed circuit boards, chip carriers, connectors (conventional, radio-frequency (RF), and fiber-optic), and other surface-mount components), microelectromechanical systems (MEMS), automotive applications (including components for ignition and transmission systems, lamp sockets, pump components, coil forms, and sensors), printer/copier/fax components, cookware, high-barrier/retort-processed food containers, plus components for chemical processing (including pumps, meters, and valves).

 

Commonly processed by injection molding, LCP parts can be joined using many thermoplastic welding techniques, especially ultrasonic and laser welding.


Owing to the highly rigid structure of their molecular chains, the weak van der Waals forces between molecular chains, and their liquid crystalline nature — which tend to be nearly linear and to occupy a stacked orientation that maintains its order regardless of solid or liquid phase — LCP polymer chains align easily in the flow direction and are highly anisotropic.

 

This not only accounts for their good mechanical properties, which results from the self-reinforcing orientation, but also for the high flow and molding productivity that characterize these materials.

 

Most thermoplastics and especially fiber-reinforced thermoplastics exhibit some anisotropy after processing. However, molded properties of LCPs can vary significantly between flow and cross-flow directions. Hence, care should be used when designing parts and tools for LCPs to take advantage of (and avoid the challenges of) this characteristic.


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SumikaSuper SR1205L retains more of its tensile strength at high temperatures (120°C), relative humidity levels (100% RH), and pressures (2 atm) than conventional LCP polymers after 200 hours of testing.


High anisotropy means weldlines (where flow fronts with different molecular orientations converge) are weaker and prone to warpage and thermal-expansion differentials. Hence, LCPs are typically reinforced with glass fiber and mineral fillers — not so much to increase stiffness and strength but to reduce anisotropy. Warpage also can be reduced with proper gate design in the tool.


However, given their high melt flow rates, fast setup times, and low thermal expansion in the direction of flow, LCPs can be formed into thin-wall parts with short molding cycles that deliver high performance at low mass and lower material usage — all of which help offset higher initial material costs.

 

The thermal stability typical of LCPs enables processors to efficiently reuse regrind and recycle reject parts, which again reduces material losses and lowers effective part cost.

 

Depending on design and thickness requirements of a given connector program, Sumitomo Chemical can help electrical engineers select a suitable LCP grade and provide appropriate data to help engineers design components better, faster, and with higher value.

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